A new cobalt metal-organic framework as a substrate for Pd nanoparticles applied in high-efficiency nitro phenol degradation and cinnamaldehyde hydrogenation

Zhida Liu; Liangmin Ning; Kaiyuan Wang; Lixi Feng; Wen Gu; Xin Liu

doi:10.1039/c9dt04051j

A new cobalt metal-organic framework as a substrate for Pd nanoparticles applied in high-efficiency nitro phenol degradation and cinnamaldehyde hydrogenation

Dalton Trans. 2020 Jan 28;49(4):1191-1199. doi: 10.1039/c9dt04051j.

Authors

Zhida Liu¹, Liangmin Ning, Kaiyuan Wang, Lixi Feng, Wen Gu, Xin Liu

Affiliation

¹ College of Chemistry, Key Laboratory of Advanced Energy Materials Chemistry(MOE), Tianjin Key Laboratory of Metal and Molecule Based Material Chemistry, Collaborative Innovation Centre of Chemical Science and Engineering, Nankai University, Tianjin, 300071, China. liuxin64@nankai.edu.cn guwen68@nankai.edu.cn.

PMID: 31898695
DOI: 10.1039/c9dt04051j

Abstract

In recent years, attributed to the excellent catalytic performance of precious metal materials, metal nanoparticles@MOF catalyst has been a popular research direction. Herein, we have synthesized a new 3D cobalt metal-organic framework [Co(TATAB)(344-pytpy)·DMF]n(H3TATAB = 4,4',4″-s-triazine-1,3,5-triyltri-p-aminobenzoic acid; 344-pytpy = 4'-(3-pyridyl)-4,2':6',4″-terpyridine)(1)(P1) by solvothermal method. Its crystal structure was determined with single-crystal X-ray diffraction (SC-XRD) techniques. The final composite Pd-NPs@1 catalyst was synthesized by a reduction method. The catalyst showed high catalytic performance and high recycling stability for nitrophenol degradation and cinnamaldehyde hydrogenation reaction.