Preliminary study on the electrocatalytic performance of an iron biochar catalyst prepared from iron-enriched plants

Abstract

Eichhornia crassipes is a hyperaccumulator of metals and has been widely used to remove metal pollutants from water, but disposal of contaminated plants is problematic. Biochar prepared from plants is commonly used to remediate soils and sequester carbon. Here, the catalytic activity of biochar prepared from plants enriched with iron was investigated as a potentially beneficial use of metal-contaminated plants. In a 30-day hydroponic experiment, E. crassipes was exposed to different concentrations of Fe(III) (0, 4, 8, 16, 32 and 64 mg/L), and Fe-biochar (Fe-BC) was prepared by pyrolysis of the plant roots. The biochar was characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectrometry (EDS), Brunauer-Emmett-Teller (BET) analysis, X-ray photoelectron spectroscopy (XPS) and atomic absorption spectrometry (AAS). The original root morphology was visible and iron was present as γ-Fe₂O₃ and Fe₃O₄. The biochar enriched with Fe(III) at 8 mg/L (8-Fe-BC) had the smallest specific surface area (SSA, 13.54 m²/g) and the highest Fe content (27.9 mg/g). Fe-BC catalytic activity was tested in the electrocatalytic reduction of H₂O₂ using cyclic voltammetry (CV). The largest reduction current (1.82 mA/cm²) was displayed by 8-Fe-BC, indicating the highest potential catalytic activity. We report here, for the first time, on the catalytic activity of biochar made from iron-enriched plants and demonstrate the potential for reusing metal-contaminated plants to produce a biochar catalyst.

Keywords: Eichhornia crassipes; Fe-doped biochar; H(2)O(2) electrocatalysis; Hyperaccumulator.