Ultrasonic-Assisted Synthesis of Highly Defined Silver Nanodimers by Self-Assembly for Improved Surface-Enhanced Raman Spectroscopy

Chemistry. 2020 Jan 27;26(6):1243-1248. doi: 10.1002/chem.201904518. Epub 2020 Jan 21.

Abstract

Considerable research efforts have been devoted to surface-enhanced Raman spectroscopy (SERS), due to its excellent performance in biosensing and imaging. Here, a novel and facile strategy for the fabrication of well-defined and uniform nanodimers as SERS substrates is presented. By the assistance of ultrasound, the violent polyol process for particle generation becomes controllable, enabling the self-assembly of nanostars to nanodimers. Moreover, the aggregation of nanodimers can be easily tuned by post-ultrasonic treatment, which gives a sensitive substrate for SERS.

Keywords: aggregation; nanodimers; self-assembly; surface-enhanced Raman spectroscopy; ultrasonic-assisted synthesis.