1,4-Dioxane contamination of German drinking water obtained by managed aquifer recharge systems: Distribution and main influencing factors

Abstract

1,4-Dioxane, a cyclic ether that has been classified as a class 2B carcinogen by the US-EPA, is a substance of growing environmental concern because of its abundant occurrence in surface waters worldwide. Its high polarity and low biodegradability hamper its retardation in aquifer systems. Previous investigations in Germany have shown that 1,4-dioxane is already widely distributed in rivers and can be found in groundwater at contamination sites. Therefore, the present study shall provide an overview of the Germany-wide distribution of 1,4-dioxane in finished drinking water (FDW) obtained by managed aquifer recharge (MAR) systems. Thus, we investigated the 1,4-Dioxane levels in FDW obtained by MAR, such as river bank filtration (RBF) or artificial groundwater recharge (AGR), in regions that are supplied by surface water bodies (mainly rivers) with already known 1,4-dioxane contaminations. In total, 125 FDW samples and 33 samples of corresponding surface waters were analyzed for 1,4-dioxane content using solid phase extraction followed by gas chromatography-mass spectrometry (SIM-mode) using a slight modification to US-EPA method 522. About 80% of the investigated FDW samples contained 1,4-dioxane at levels exceeding the limit of quantification (0.034 μg/L); the maximum value was 2.05 μg/L. However, a maximum concentration of 3 μg/L was obtained in the surface water samples. Three main factors were associated with elevated levels of 1,4-dioxane in the FDW: A significant 1,4-dioxane contamination of the associated surface water, the application of RBF instead of AGR, and the proportion of available unpolluted groundwater and/or reservoir water blended in the individual waterworks. The results show that 1,4-dioxane should be critically monitored during FDW production by means of MAR not only in Germany. The findings are also of relevance to neighboring countries depending on the same river systems and for research in the field of small mobile substances in drinking water production in general.

Keywords: 1,4-Dioxane; Artificial groundwater recharge; Bank filtration; Drinking water; Germany.