Investigation on ultrasonic cavitation erosion of TiMo and TiNb alloys in sulfuric acid solution

W H Xian; D G Li; D R Chen

doi:10.1016/j.ultsonch.2019.104877

Investigation on ultrasonic cavitation erosion of TiMo and TiNb alloys in sulfuric acid solution

Ultrason Sonochem. 2020 Apr:62:104877. doi: 10.1016/j.ultsonch.2019.104877. Epub 2019 Nov 17.

Authors

W H Xian¹, D G Li², D R Chen¹

Affiliations

¹ State Key Laboratory of Tribology, Tsinghua University, Beijing 100084, China.
² State Key Laboratory of Tribology, Tsinghua University, Beijing 100084, China. Electronic address: dgli@mail.tsinghua.edu.cn.

PMID: 31806552
DOI: 10.1016/j.ultsonch.2019.104877

Abstract

Two kinds of Ti-alloys, i.e., TiMo and TiNb alloys are manufactured in this paper, and their ultrasonic cavitation erosion behaviors in 0.1 M H₂SO₄ solution are evaluated by the mean depth erosion (MDE), SEM and white light photograph. The results show that MDE of TiMo and TiNb alloys obviously increase with increasing the cavitation erosion time, however, they evidently decrease with the increment of Mo or Nb content at each fixed cavitation erosion time, and even some large blank areas (uneroded areas) still exist on the sample surface after ultrasonic cavitation erosion for 2 h in the case of Ti10Mo and Ti20Nb samples, implying the enhanced anti-cavitation erosion property of Ti-alloy by adding Mo or Nb element. The MDE of Ti10Mo or Ti20Nb sample is lower than that of TC4 sample in the case of each cavitation erosion time, indicating the better cavitation erosion resistance of of Ti10Mo or Ti20Nb sample. The influences of Mo and Nb on the passivity of TiMo and TiNb alloys during the ultrasonic cavitation erosion are detected by potentiodynamic curves. The results display that Ti, TC4, TixMo (x = 1, 5, 10) and TixNb (x = 5, 10, 20) samples are all almost in the passive state within the potential region from 0V_SCE to 1.5V_SCE during ultrasonic cavitation erosion, and the passive current density evidently decreases with increasing Mo or Nb content, indicating the enhanced passive characteristic by adding Mo or Nb alloys during the ultrasonic cavitation erosion.

Keywords: Mean depth erosion; Passive film; Ti-alloy; Ultrasonic cavitation erosion.