Synthetic Photoelectrochemistry

Abstract

Photoredox catalysis (PRC) and synthetic organic electrochemistry (SOE) are often considered competing technologies in organic synthesis. Their fusion has been largely overlooked. We review state-of-the-art synthetic organic photoelectrochemistry, grouping examples into three categories: 1) electrochemically mediated photoredox catalysis (e-PRC), 2) decoupled photoelectrochemistry (dPEC), and 3) interfacial photoelectrochemistry (iPEC). Such synergies prove beneficial not only for synthetic "greenness" and chemical selectivity, but also in the accumulation of energy for accessing super-oxidizing or -reducing single electron transfer (SET) agents. Opportunities and challenges in this emerging and exciting field are discussed.

Keywords: electrochemistry; mediators; photoelectrochemistry; photoelectrodes; photoredox catalysis.