Bisfenol A adsorption using a low-cost adsorbent prepared from residues of babassu coconut peels

Environ Technol. 2021 Jun;42(15):2372-2384. doi: 10.1080/09593330.2019.1701568. Epub 2019 Dec 11.

Abstract

Nowadays, the occurrence of microcontaminants in water resources has become a worldwide concern. Among them, it can be mentioned Bisphenol A, a substance widely used in the chemical composition of plastic such as manufacture of packages, bottles, toiletries, among others. Its use may cause adverse effects on human health and the environment. Thus, a treatment is necessary to remove this compound and adsorption is an interesting alternative due to its low cost, operation and high efficiency. The objective of the present study was to evaluate the adsorption capacity of bisphenol in babassu activated carbon. The obtained results were satisfactory and the best experimental conditions were at 318 K temperature, 1 g L-1 adsorbent concentration and 720 min equilibrium time, resulting in the maximum adsorptive capacity of 49.61 mg g-1. The experimental data fit best with the pseudo-second order and Langmuir models for the kinetic and equilibrium studies, respectively. Thermodynamic parameters indicated endothermic, spontaneous and reversible process. The main adsorption mechanisms were hydrogen bonds and π-π interactions. In addition, the material regeneration study allowed to verify its possibility of reuse. Therefore, it was noticed that babassu activated carbon has high potential applicability in the treatment of contaminated water.

Keywords: Babassu; Bisphenol A; emerging pollutants; low-cost adsorbent.

MeSH terms

  • Adsorption
  • Charcoal
  • Cocos
  • Humans
  • Hydrogen-Ion Concentration
  • Kinetics
  • Temperature
  • Thermodynamics
  • Water Pollutants, Chemical* / analysis
  • Water Purification*

Substances

  • Water Pollutants, Chemical
  • Charcoal