A novel mesoporous hydrogen-bonded organic framework with high porosity and stability

Bin Wang; Xiu-Liang Lv; Jie Lv; Li Ma; Rui-Biao Lin; Hui Cui; Jian Zhang; Zhangjing Zhang; Shengchang Xiang; Banglin Chen

doi:10.1039/c9cc07802a

A novel mesoporous hydrogen-bonded organic framework with high porosity and stability

Chem Commun (Camb). 2019 Dec 17;56(1):66-69. doi: 10.1039/c9cc07802a.

Authors

Bin Wang¹, Xiu-Liang Lv, Jie Lv, Li Ma, Rui-Biao Lin, Hui Cui, Jian Zhang, Zhangjing Zhang, Shengchang Xiang, Banglin Chen

Affiliation

¹ Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, 32 Shangsan Road, Fuzhou 350007, P. R. China. scxiang@fjnu.edu.cn.

PMID: 31790104
DOI: 10.1039/c9cc07802a

Abstract

A highly stable hydrogen-bonded organic framework, HOF-14, has been successfully constructed and structurally characterized. It possesses a permanent three dimensional (3D) porous structure. The activated HOF-14 has a high BET surface area of 2573 m2 g-1 and a record large pore volume of 1.36 cm3 g-1 among HOF materials. In addition, HOF-14 also exhibits high chemical and thermal stability and is capable of highly selective separation of light hydrocarbons under ambient conditions.