Resistive Water Sensors Based on PEDOT:PSS- g-PEGME Copolymer and Laser Treatment for Water Ingress Monitoring Systems

ACS Sens. 2019 Dec 27;4(12):3291-3297. doi: 10.1021/acssensors.9b01917. Epub 2019 Dec 13.

Abstract

Water sensors are a type of level sensor that can be used in various applications requiring the sensing of water levels, such as in dams, nuclear power plants, water pipes, water tanks, and dehumidifiers. In particular, water sensors in water ingress monitoring systems (WIMS) protect lives and property from disasters caused by water leakage and flooding. Here, a resistive water sensor for WIMS that incorporates poly(3,4-ethylenedioxythinophene):poly(styrene sulfonate) (PEDOT:PSS) grafted with poly(ethylene glycol) methyl ether (PEGME) (PEDOT:PSS-g-PEGME copolymer) as high-conductivity electrodes and laser-treated PEDOT:PSS-g-PEGME copolymer as the low-conductivity resistive component is reported. The configuration of the water sensor is modeled as two parallel resistors (Rlaser treated PEDOT:PSS||Rwater) when water comes into contact with the sensor surface. The two-resistor configuration exhibits a better performance in comparison with single-resistor configurations comprising only PEDOT:PSS-g-PEGME copolymer or laser-treated PEDOT:PSS-g-PEMGE copolymer. Moreover, PEDOT:PSS-g-PEGME copolymer is applied to the sensor to improve the stability of PEDOT:PSS in water. We demonstrate that the sensor can detect the water level in real time with high sensitivity and accuracy, and thus has potential in applications for monitoring water-related hazards.

Keywords: PEDOT:PSS; laser treatment; resistive water sensor; water ingress monitoring systems; water resistance.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Bridged Bicyclo Compounds, Heterocyclic / chemistry*
  • Bridged Bicyclo Compounds, Heterocyclic / radiation effects
  • Electrochemical Techniques / instrumentation
  • Electrochemical Techniques / methods*
  • Electrodes
  • Infrared Rays
  • Lasers
  • Polyethylene Glycols / chemistry*
  • Polyethylene Glycols / radiation effects
  • Polyethylene Terephthalates / chemistry
  • Polymers / chemistry*
  • Polymers / radiation effects
  • Polystyrenes / chemistry*
  • Polystyrenes / radiation effects
  • Water / analysis*

Substances

  • Bridged Bicyclo Compounds, Heterocyclic
  • Polyethylene Terephthalates
  • Polymers
  • Polystyrenes
  • poly(3,4-ethylene dioxythiophene)
  • Water
  • Polyethylene Glycols
  • polystyrene sulfonic acid
  • monomethoxypolyethylene glycol