Outstanding catalytic performance in the semi-hydrogenation of acetylene in a front-end process by establishing a "hydrogen deficient" phase

Qunfeng Zhang; Yiqi Xu; Qingtao Wang; Weimin Huang; Jing Zhou; Yishu Jiang; Hao Xu; Lingling Guo; Pengze Zhang; Jia Zhao; Feng Feng; Xiaonian Li

doi:10.1039/c9cc06469a

Outstanding catalytic performance in the semi-hydrogenation of acetylene in a front-end process by establishing a "hydrogen deficient" phase

Chem Commun (Camb). 2019 Dec 10;55(99):14910-14913. doi: 10.1039/c9cc06469a.

Authors

Qunfeng Zhang¹, Yiqi Xu, Qingtao Wang, Weimin Huang, Jing Zhou, Yishu Jiang, Hao Xu, Lingling Guo, Pengze Zhang, Jia Zhao, Feng Feng, Xiaonian Li

Affiliation

¹ Industrial Catalysis Institute of Zhejiang University of Technology, State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, Hangzhou, 310014, P. R. China. ffeng@zjut.edu.cn xnli@zjut.edu.cn.

PMID: 31769458
DOI: 10.1039/c9cc06469a

Abstract

Pd-[Bmim][Cl] phase was immobilized onto Al2O3 to neutralize the excessive hydrogen in the gas phase to prevent the over-hydrogenation of acetylene, thereby achieving a high selectivity for ethylene.