The present work reports the development of nanostructured material from Cashew nut shell liquid (CNSL, an agro byproduct of cashew industry, 87% cardanol) to evaluate their potential in antibacterial applications as a substitute of petroleum feedstock via an energy-efficient method. The nanostructured material was synthesized by coordination polymerization reaction of cardanol and divalent Mn(II) salt with the aid of microwave irradiations. FTIR spectroscopy was used to confirm the proposed structure of the synthesized materials. FTIR-ATR spectroscopy was employed to verify the curing of material by comparing the spectra of the cured samples with the frequencies of uncured samples. Magnetic moment and UV-visible spectroscopy were used to confirm the proposed structure of the material further. Morphology of the synthesized material was investigated by XRD, optical microscopy, SEM and TEM and thermal behaviour by TGA/DTG/DSC technique. Agar diffusion method was utilized to investigate the antibacterial activity of the synthesized material against bacterial strains E. coli, K. pneumoniae, B. subtilis and S. aureus. N2 adsorption-desorption was investigated to check BET specific surface area and BJH pore size distribution of the same. The results revealed that the synthesized materials were obtained as semicrystalline, porous, thermally stable and nanostructured film forming materials with moderate to good antibacterial activity against different nosocomial bacteria. They can be used as thermally stable antibacterial agents in the field of films/coatings for health care applications.
Keywords: Amorphous; CNSL; Coordination polymer; Layered; Microwave-assisted synthesis; Nanostructured; Porous.
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