The combination of eco-respectful epoxy compounds with the humins, a by-product of biomass chemical conversion technologies, allow the obtention of materials with high added value. In this work, we propose a chemical connection study of humins with two aliphatic bis-epoxides through copolymerization reactions to synthesize sustainable, bio-based thermosets. The mechanism insights for the crosslinking between the epoxides and humins was proposed considering the different functionalities of the humins structure. Fourier Transform InfraRed (FT-IR), one dimensional (1D) and two-dimensional (2D) Nuclear Magnetic Resonance (NMR) spectroscopy techniques were used to build the proposed mechanism. By these techniques, the principal chain connections and the reactivity of all the components were highlighted in the synthesized networks.
Keywords: biomass; epoxy resins; green chemistry; humins; mechanims; thermosets.