How to prevent the agglomeration of nanoparticles in nanocomposites remains a key challenge. Using nanometer suspension as a doping agent provides an effective approach to solve this challenge. A new technique that consists of chemical coprecipitation, ball milling and sedimentation separation metheds was developed for preparing hard magnetic M-type BaFe12O19 nanometer suspension. The single-phase BaFe12O19 nanoparticles dispersed uniformly in alcohol have been prepared by this new technique. Magnetic nanocomposite thermoelectric materials with a homogeneous dispersion of BaFe12O19 nanoparticles were prepared through a combination process of an ultrasonic mixing of BaFe12O19 nanometer suspension and In-filled CoSb3 thermoelectric matrix material and spark plasma sintering. The microstructure analysis of magnetic nanocomposite thermoelectric materials confirmed that using the nanometer suspension as a doping agent is an effective way to solve the agglomeration phenomenon of nanoparticles in nanocomposites. In addition, the decline of thermoelectric performance in the high-temperature intrinsic excitation region of In-filled CoSb3 can be effectively suppressed by the magnetic phase transition of BaFe12O19 nanoparticles dried by nanometer suspension from ferromagnetism to paramagnetism. It is also confirmed that using the BaFe12O19 nanometer suspension as a thermoelectric performance enhancer is an effective way to solve the challenging problem of performance deterioration of thermoelectric materials at high temperature.
Keywords: BaFe12O19 nanometer suspension; In-filled CoSb3 material; magnetic nanocomposites; thermoelectric properties; uniform dispersion.