A sample preparation method, QuEChERS extraction combined with a magnetic micro dispersive solid phase extraction (MµdSPE), was optimized and evaluated for the trace analysis of 9 brominated flame retardants in red fruit samples (strawberries, blueberries, and raspberries) using gas chromatography-mass spectrometry. Magnetic nanomaterials were used as sorbents providing an extraction of the target compounds. Linearity was established for all the analytes (from 10 to 200 µg kg-1). Seven concentration levels were analyzed with three measurements at each concentration. Linear responses (R2 > 0.99) were obtained, recoveries of all target analytes were within the range of 65-141%, relative standard deviations were <20% at all three spiking levels, while intraday and interday precisions were below 20%. This study demonstrated that the new sample preparation with magnetic nanoparticles could potentially be expanded to extract and pre-concentrate the BFRs in different red fruit samples. The method has been successfully applied to study BFRs in 12 samples from conventional and organic farming.
Keywords: Flame retardants; GC/MS; Magnetic nanoparticles; Micro solid phase extraction; QuEChERS; Red fruits.
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