Alginate-stabilized thixotropic emulsion gels and their applications in fabrication of low-fat mayonnaise alternatives

Int J Biol Macromol. 2020 Mar 1:146:821-831. doi: 10.1016/j.ijbiomac.2019.10.050. Epub 2019 Nov 11.

Abstract

In this study, a series of emulsion gels were prepared by dispersing emulsified oil droplets into alginate (Alg) gel matrix, and the final emulsion gels contained 2% Alg (w/v), 0.5% Tween 80 (v/v) and gradient concentrations of oil phase fractions (5-30%, v/v). Subsequently, the effects of Ca2+ addition, heating, and freeze thawing treatments on the emulsion gels were also investigated by a combination of rheological tests, confocal and scanning electron microscopy techniques. It was found that within the range of 0-30% of oil phase fraction, 0-0.15% of CaCl2 addition (w/v), all the emulsion gels could achieve significant thixotropy and good emulsion stability, without discernible oil droplet coalescence observed after heating and/or freeze thawing treatments. The yield stress value and gel stiffness increased with increasing oil phase fraction and Ca2+ addition, which is attributed to the strengthened gel network cross-links in the emulsion gels, as confirmed by SEM results. Interestingly, after freeze thawing treatment, the gel stiffness was slightly improved, which may be due to the intermolecular self-association of Alg during freezing stage. Overall, these results show the potential application of Alg-stabilized emulsion gels in preparation of low-fat mayonnaise products and other similar emulsion foods.

Keywords: Alginate; Emulsion gels; Mayonnaise; Rheological properties.

MeSH terms

  • Alginates / chemistry*
  • Calcium / chemistry
  • Emulsions / chemistry*
  • Freezing
  • Gels / chemistry*
  • Lipids / chemistry*
  • Oils / chemistry
  • Rheology
  • Temperature

Substances

  • Alginates
  • Emulsions
  • Gels
  • Lipids
  • Oils
  • Calcium