Carbon-Based Nanomaterials via Heterojunction Serving as Photocatalyst

Front Chem. 2019 Oct 24:7:713. doi: 10.3389/fchem.2019.00713. eCollection 2019.

Abstract

Photocatalytic hydrogen production from water splitting is of auspicious possibility to resolve the energy shortage and environmental anxieties. In the past decade, the combination of different carbon-based allotropes with semiconductors of different structure and unique properties to construct heterojunction, which can improve the charge separation, light absorption, and steadiness, offer a promising way to achieve efficient photocatalyst. This review aims to provide an overview of the development for the carbon nanomaterials (CNMs)-based photocatalysts used for hydrogen production from water splitting and photocatalytic degradation of organic pollutants in waste water. The recent progress of CNMs-based heterojunction, including various composite with graphene, fullerene, carbon quantum dots (CQDs), and carbon nanotubes (CNTs) were highlighted. Furthermore, a typical model of CNMs-based Z-scheme heterojunction was also addressed. Finally, a promising perspective on the future development of CNMs-based photocatalysts have been discussed.

Keywords: carbon nanomaterials (CNMs); heterojunction; hydrogen production; photocatalysts; water splitting.

Publication types

  • Review