Understanding reactions and pore-forming mechanisms between waste cotton woven and FeCl3 during the synthesis of magnetic activated carbon

Abstract

FeCl₃ is a valuable iron salt used in the synthesis of magnetic waste cotton woven-based activated carbon. Although it has received extensive research attention, more information is required regarding its interactions with the carbon matrix. This systematic study describes the potential reactions of FeCl₃ and waste cotton woven. First, the textural properties of waste cotton woven-based activated carbon synthesized under various conditions were investigated via element analysis, N₂ sorption/desorption isotherms, and scanning electron microscopy. Then, the possible reaction mechanisms were deduced through various characterization methods. The results demonstrate that FeCl₃ can lower the initial decomposition temperature of WCW to 135 °C and catalyze decarboxylation and decarbonylation at 100-330 °C to elevate the formation of microporous structures. Moreover, FeCl₃ can also form Lewis acid sites at 330-700 °C and promote the cross-linking reaction to develop intricate microporous structures and carbonaceous materials with the synergistic effect of Fe³⁺ and Cl^-. FeCl₃ could be used as a template-like agent to form mesoporous structures. Meanwhile, it can also act as a magnetizer that Fe₃O₄ derived from the decomposition of FeCl₃ would insert into the carbon matrix and combine with C-Cl to tailor the magnetic controllable activated carbon. Finally, we confirmed that extending the activation time could convert the structure of waste cotton woven-based activated carbon and increase the number of active sites, thereby further improving the catalytic properties of FeCl₃ in pore formation.

Keywords: FeCl(3); Magnetic activated carbon; Pore-forming; Reaction mechanisms; Waste cotton woven.