Determination of thiourea based on the reversion of fluorescence quenching of nitrogen doped carbon dots by Hg2

Abstract

Herein, a facile and quick strategy to detect thiourea was conducted based on the reversion of fluorescence quenching of nitrogen doped carbon dots (NCDs) by Hg²⁺. The NCDs with good water solubility and 17% of quantum yield was synthesized by one-step hydrothermal method, using ammonium citrate and dextrin as carbon source and nitrogen source, respectively. The fluorescence of NCDs was obviously quenched by Hg²⁺ and can be recovered, due to stronger interaction between thiourea and Hg²⁺. There was a good linear relationship between the recovered fluorescence and the concentration of thiourea within range of 0.90-10.0 μM and the detection limit for thiourea detection was 0.15 μM. The as-prepared NCDs can be used for determination of thiourea in tap water, lake water and rice flour products, and the spike recoveries were between 91.6 and 108%.

Keywords: Determination; Fluorescence quenching; Fluorescence recovering; Hg(2+); Nitrogen doped carbon dots; Thiourea.