In the promotion of energy strategies to address the global energy crisis, nanotechnology has been successfully used to generate novel energy materials with excellent characteristics, such as high specific surface area, good flexibility and large porosity. Among the various methods for fabricating nanoscale materials, electrospray and electrospinning technologies have unlocked low-cost, facile and industrial routes to nanotechnology over the past ten years. This review highlights research into the key parts and primary theory of these techniques and their application in preparing energy-related materials and devices: especially fuel cells, solar cells, lithium ion batteries, supercapacitors as well as hydrogen storage systems. The challenges and future prospects of the manufacturing technologies are also covered in this paper.