Forward osmosis with an algal draw solution to concentrate municipal wastewater and recover resources

Abstract

This study aimed to concentrate and recover resources from municipal wastewater with a novel forward osmosis (FO) system. The FO system used synthetic seawater as the draw solution (DS) to extract water from the feed solution (FS) (synthetic raw municipal wastewater). Because ammonium passed through the FO membrane from the FS to the DS, we cultivated an algal strain (Chlorella vulgaris) in the DS to remove and recover ammonium. For three consecutive FO cycles, the algal FO system removed 35.4% of the ammonium from the DS, increased the concentrations of COD and ${\text{PO}}_4^{3-}-P$ in the FS by 43.0%, and achieved a water flux of 11.59 ± 0.49 L m^-2 hr^-1 . Throughout the FO cycles, the algal biomass concentration of the DS stayed at 606 ± 29 mg COD/L due to simultaneous algal growth and DS dilution. This FO process may be feasible to implement for full-scale applications to concentrate wastewater and recover resources. PRACTITIONER POINTS: A novel forward osmosis (FO) system with an algal draw solution (DS) concentrated municipal wastewater and recovered resources (ammonium). Ammonium but not organic matter or phosphate diffused across the FO membrane from the feed solution (FS) to the DS. The algal FO system increased COD/phosphate concentration in the FS by 43.0% and removed 35.4% of ammonium from the DS. The water fluxes in the algal FO system and the control were 11.59 and 12.02 L m^-2 hr^-1 , respectively. The novel algal FO process has the potential to improve full-scale efficiency by concentrating municipal wastewater and recovering nutrients.

Keywords: Chlorella vulgaris; alga; ammonium; draw solution; feed solution; forward osmosis; municipal wastewater; nutrients; resource recovery; thin-film composite membrane.