The initial coalescence of a pendant drop at bulk liquid was jointly investigated by an ultrahigh-speed DC electrical device, a high-speed camera, and a fast micro-Particle Image Velocimetry (micro-PIV). Extended to highly viscous non-Newtonian liquids, the variation of the coalescing width vs time confirms the distinct regimes reported for drop-drop configuration: linear in the inertially limited viscous regime; square root in the inertial regime; possibly a transient viscous regime in between with a logarithmic correction. The measured flow fields during coalescence reveal the transformation of surface energy to kinetic energy, so that the highly located inertia could play a dominant role in relation to the viscous force.