Introducing fluorene into organic hole transport materials to improve mobility and photovoltage for perovskite solar cells

Jiang-Yang Shao; Ning Yang; Wang Guo; Bin-Bin Cui; Qi Chen; Yu-Wu Zhong

doi:10.1039/c9cc06155j

Introducing fluorene into organic hole transport materials to improve mobility and photovoltage for perovskite solar cells

Chem Commun (Camb). 2019 Nov 5;55(89):13406-13409. doi: 10.1039/c9cc06155j.

Authors

Jiang-Yang Shao¹, Ning Yang², Wang Guo¹, Bin-Bin Cui², Qi Chen², Yu-Wu Zhong³

Affiliations

¹ CAS Key Laboratory of Photochemistry, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Beijing 100190, China. zhongyuwu@iccas.ac.cn.
² Advanced Research Institute of Multidisciplinary Science, Beijing Institute of Technology, Beijing 100081, P. R. China. cui-chem@bit.edu.cn.
³ CAS Key Laboratory of Photochemistry, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Beijing 100190, China. zhongyuwu@iccas.ac.cn and School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049, China.

PMID: 31637391
DOI: 10.1039/c9cc06155j

Abstract

A new small molecular hole-transporting material, 1,3,6,8-tetrakis[N-(p-methoxyphenyl)-N'-(9,9'-dimethyl-9H-fluoren-2-yl)-amino]pyrene (TFAP) was synthesized and applied in CH3NH3PbI3-perovskite solar cells. A best power conversion efficiency of 19.7% with a photovoltage of 1.11 V has been achieved.