Photoinduced Two-Body Loss of Ultracold Molecules

Phys Rev Lett. 2019 Sep 20;123(12):123402. doi: 10.1103/PhysRevLett.123.123402.

Abstract

The lifetime of nonreactive ultracold bialkali gases was conjectured to be limited by sticky collisions amplifying three-body loss. We show that the sticking times were previously overestimated and do not support this hypothesis. We find that electronic excitation of NaK+NaK collision complexes by the trapping laser leads to the experimentally observed two-body loss. We calculate the excitation rate with a quasiclassical, statistical model employing ab initio potentials and transition dipole moments. Using longer laser wavelengths or repulsive box potentials may suppress the losses.