Tremendous energy consumption is required for traditional artificial N2 fixation, leading to additional environmental pollution. Recently, new Li-N2 batteries have inextricably integrated energy storage with N2 fixation. In this work, graphene is introduced into Li-N2 batteries and enhances the cycling stability. However, the instability and hygroscopicity of the discharge product Li3 N lead to a rechargeable but irreversible system. Moreover, strong nonpolar N≡N covalent triple bonds with high ionization energies also cause low efficiency and irreversibility of Li-N2 batteries. In contrast, the modification with in situ generated Li3 N and LiOH restrained the loss and volume change of Li metal anodes during stripping and plating, thereby promoting the rechargeability of the Li-N2 batteries. The mechanistic study here will assist in the design of more stable Li-N2 batteries and create more versatile methods for N2 fixation.
Keywords: batteries; energy storage; graphene; nitrogen fixation; surface analysis.
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