Characterization of highly effective plasma-treated g-C3N4 and application to the photocatalytic H2O2 production

Abstract

Plasma treated g-C₃N₄ (PT-g-C₃N₄) was obtained by a simple and rapid DBD plasma modification process on the pristine g-C₃N₄. Compared with the pristine g-C₃N₄, the grain size of the PT-g-C₃N₄ decreased from 99.2 nm to 57.2 nm, the specific surface area and the pore volume increased by 15% and 33.8%, respectively. Oxygen-containing groups such as -NO₂ and -COOH were observed to form on the surface of PT-g-C₃N₄ so the hydrophilic property of PT-g-C₃N₄ was much higher than that of pristine g-C₃N₄. More importantly, the photocatalytic H₂O₂ production activity of PT-g-C₃N₄ was significantly improved on account of the treatment in plasma atmosphere for only 5 min, the H₂O₂ yield of which was about 13 times that of the pristine g-C₃N₄. Our finding is not only of great significance for effectively promoting the production of H₂O₂ under mild conditions, but also proposes an innovative DBD plasma method to modify the g-C₃N₄ photocatalyst, which effectively promotes the improvement of photocatalytic activity and provides valuable insights for catalyst modification studies.

Keywords: DBD plasma; H(2)O(2) production; Photocatalyst; g-C(3)N(4).