A novel flame-retardant composite material based on zinc alginate (ZnAlg) and nano-cuprous oxide (Cu2O) was prepared through a simple, eco-friendly freeze-drying process and a sol-gel method. The composites were characterized and their combustion and flammability behavior were tested. The composites had high thermal stability and achieved nearly non-flammability with a limiting oxygen index (LOI) of 58. The results show remarkable improvement of flame-retardant properties in the ZnAlg/Cu2O composites, compared to ZnAlg. Furthermore, the pyrolysis behavior was determined by pyrolysis-gas chromatography-mass spectrometry (Py-GC-MS) and the flame-retardant mechanism was proposed based on the combined experimental results. The prepared composites show promising application prospects in building materials and the textile industry.
Keywords: flame retardancy; nano-Cu2O; pyrolysis; thermal degradation; zinc alginate.