Study on the changes of ultrasonic parameters over supercritical Ni-Co electroplating process

Ho-Chiao Chuang; Guan-Wei Jiang; Jorge Sanchez

doi:10.1016/j.ultsonch.2019.104805

Study on the changes of ultrasonic parameters over supercritical Ni-Co electroplating process

Ultrason Sonochem. 2020 Jan:60:104805. doi: 10.1016/j.ultsonch.2019.104805. Epub 2019 Sep 20.

Authors

Ho-Chiao Chuang¹, Guan-Wei Jiang², Jorge Sanchez²

Affiliations

¹ Department of Mechanical Engineering, National Taipei University of Technology, Taipei 10608, Taiwan. Electronic address: hchuang@mail.ntut.edu.tw.
² Department of Mechanical Engineering, National Taipei University of Technology, Taipei 10608, Taiwan.

PMID: 31563001
DOI: 10.1016/j.ultsonch.2019.104805

Abstract

This work discusses the influence of changes to ultrasound (US) parameters over the nickel cobalt (Ni-Co) metal thin film properties produced by supercritical CO₂ (SC-CO₂) electroplating. Additionally, Ni-Co films were produced by conventional electroplating and silent SC-CO₂ and compared against each other. The discussion on metal thin film properties revolves around variations to the bath type ultrasonic power (15 W and 20 W) and frequency (42 k Hz and 72 kHz) during experiments. The properties provided by the three electroplating processes and analyzed include: grain sizes, film elemental content analyses, surface microstructures, film hardness, corrosion resistance, surface roughness, crystalline structure and preferential growth, etc. From the results it was clear that quality of films produced by US-SC-CO₂ was improved compared to that of films produced by silent SC-CO₂, which itself was better than those produced by conventional electroplating. However, when US power was varied we observed a decline in the mechanical properties of the produced films. The combination of ultrasonic agitation with SC-CO₂ allows for improved mechanical properties such as: lower surface roughness, finer grain size and surface morphologies, increased corrosion resistance and film hardness. The ultrasound agitation applied to SC-CO₂ electroplating enhanced the formation of alloyed metal as ultrasonic agitation increased the electrolyte flowability during electroplating process resulting in increased mass transfer while at the same time achieving a surface cleaning effect which removed metal ions with poor adhesion and other unwanted particles. Moreover, application of ultrasonic agitation avoids the use of surfactants so only changes to the physical phenomena and no changes to the chemical composition of the deposited thin films were observed, meaning less pollution to the electrolyte and higher purity of the deposited films. The US-SC-CO₂ electroplating method described in this work effectively enhanced the mechanical properties of the deposited thin films compared to those produced by both silent SC-CO₂ and conventional electroplating processes.

Keywords: Alloy coating; Nickel-cobalt; SC-CO(2); Ultrasonic electroplating.