Synthesis and application of V2O5-CeO2 nanocomposite catalyst for enhanced degradation of methylene blue under visible light illumination

Abstract

Methylene blue dye is among the toxic, mutagenic, and carcinogenic pollutants. Hence, its treatment via photocatalytic degradation is an important remediation method for the sake of a healthy environment. Herein, the V₂O₅-CeO₂ nanocomposite catalysts were synthesized via a simple precipitation-thermal decomposition approach and used for the photodegradation of methylene blue in the presence of H₂O₂ as an effective electron scavenger under visible light illumination. The nanocomposite catalysts were systematically characterized to investigate the effects of V₂O₅ with the aids of X-ray, morphology, light absorption, catalytic activity, and charge transfer properties of the nanocomposite catalysts. The VC-2 nanocomposite prepared with NH₄VO₃:CeO₂ molar ratios at 0.15:1 was found to be the best efficient catalyst where ≥98% of methylene blue was degraded within 25 min irradiation time. From the kinetics analysis, its rate constant was found to be higher than those of the pure V₂O₅ and CeO₂ catalysts by a factor of 12.0 and 13.5, respectively. The plausibly mechanistic elucidation of charge transfer and utilization of reactive species are conspicuous allegations of the combined effects of the nanocomposite catalyst, H₂O₂ sacrificial agent, and visible light for the photodegradation of the dye.

Keywords: Electron scavenger; Methylene blue; Nanocomposite catalyst; Photodegradation; V(2)O(5)-CeO(2).