The evaporation of desulfurization wastewater using flue gas has been considered as a promising technique. However, the release of HCl during the evaporation hinders the application of this technique. Herein, we investigated the evaporation in a laboratory-scale flue duct through experimental and numerical methods. The influences of operating parameters on characteristics of evaporation and HCl release were experimentally explored. The results show that when inlet gas temperature increases from 200°C to 350°C, gaseous HCl concentration significantly increases from 5.02 ppm to 70.96 ppm and HCl release ratio accordingly increases from 1.57% to 17.32%. However, when the wastewater only contains CaCl2, the HCl release is effectively inhibited. Subsequently, the established CFD model was validated with the experiments. It was found that relative deviations between predicted and experimental outlet gas temperatures mostly locate within the range of -10%∼0%. The negative deviations are attributed to the neglect of the crust formation. Numerical studies also reveal that droplet evaporation temperature is close to the wet-bulb temperature of the inlet gas ranging from 321.47 K to 337.85 K. Moreover, thermodynamic analysis shows that when the wastewater contains equimolar MgCl2 and CaCl2, MgCl2·6H2O first crystalizes at about d/d0 = 0.3. However, when the wastewater only contains CaCl2, CaCl2·2H2O begins to crystallize at about d/d0 = 0.25. Before crystallization, the equilibrium partial pressure of HCl is close to 0 Pa, indicating the HCl is mainly released at the particle drying stage. Further analysis suggests HCl should be mainly released from the decomposition of MgCl2·6H2O into MgOHCl.
Keywords: Desulfurization wastewater; HCl release; evaporation simulation; flue gas evaporation; zero liquid discharge.