A Novel One-Dimensional Porphyrin-Based Covalent Organic Framework

Miao Zhang; Ruijin Zheng; Ying Ma; Ruiping Chen; Xun Sun; Xuan Sun

doi:10.3390/molecules24183361

A Novel One-Dimensional Porphyrin-Based Covalent Organic Framework

Molecules. 2019 Sep 16;24(18):3361. doi: 10.3390/molecules24183361.

Authors

Miao Zhang^{1

2}, Ruijin Zheng^{3

4}, Ying Ma⁵, Ruiping Chen⁶, Xun Sun^{7

8}, Xuan Sun⁹

Affiliations

¹ State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China. 201411920@mail.sdu.edu.cn.
² Key Laboratory of Functional Crystal Materials and Device, Shandong University, Ministry of Education, Jinan 250100, China. 201411920@mail.sdu.edu.cn.
³ State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China. 201611943@mail.sdu.edu.cn.
⁴ Key Laboratory of Functional Crystal Materials and Device, Shandong University, Ministry of Education, Jinan 250100, China. 201611943@mail.sdu.edu.cn.
⁵ Key Laboratory of Colloid and Interface Chemistry, Shandong University, Ministry of Education, Jinan 250100, China. maying@sdu.edu.cn.
⁶ State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China. rchen@fjirsm.ac.
⁷ State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China. sunxun@sdu.edu.cn.
⁸ Key Laboratory of Functional Crystal Materials and Device, Shandong University, Ministry of Education, Jinan 250100, China. sunxun@sdu.edu.cn.
⁹ Key Laboratory of Colloid and Interface Chemistry, Shandong University, Ministry of Education, Jinan 250100, China. sunxuan@sdu.edu.cn.

Abstract

A novel one-dimensional covalent organic framework (COF-K) was firstly designed and synthesized through a Schiff-based reaction from a porphyrin building block and a nonlinear right-angle building block. The COF-K exhibited high BET surface area and narrow pore size of 1.25 nm and gave a CO₂ adsorption capacity of 89 mg g^-1 at 273K and 1bar.

Keywords: covalent organic frameworks; one-dimensional structure; porous material.

MeSH terms

Metal-Organic Frameworks / chemistry*
Molecular Structure
Porosity
Porphyrins / chemistry*
Spectrum Analysis

Substances

Metal-Organic Frameworks
Porphyrins

Abstract

MeSH terms

Substances

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