Halogen Bonding beyond Crystals in Materials Science

J Phys Chem B. 2019 Nov 7;123(44):9281-9290. doi: 10.1021/acs.jpcb.9b07035. Epub 2019 Oct 7.

Abstract

Halogen bonding has recently gained well deserved attention in present-day research for its importance in many fields of supramolecular science and crystal engineering. Although generally overlooked in comprehensive studies in the past, halogen bonding has become an important tool also in the field of materials science. An increased number of scientific reports are published every year where halogen bonding is exploited in soft materials rather than in crystal engineering. Here, we focus on a description of the most exciting contemporary developments in the field of halogen-bonded functional soft materials, assembled using the guiding principles of crystal engineering. We give a particular emphasis to those published in the past few years.

Publication types

  • Research Support, Non-U.S. Gov't