Cobalt-Catalyzed Cross-Coupling Reactions of Aryl Triflates and Lithium Arylborates

Hung A Duong; Zong-Han Yeow; Yong-Lun Tiong; Nur Haidah Binte Mohamad Kamal; Wenqin Wu

doi:10.1021/acs.joc.9b02105

Cobalt-Catalyzed Cross-Coupling Reactions of Aryl Triflates and Lithium Arylborates

J Org Chem. 2019 Oct 4;84(19):12686-12691. doi: 10.1021/acs.joc.9b02105. Epub 2019 Sep 18.

Authors

Hung A Duong¹, Zong-Han Yeow¹, Yong-Lun Tiong¹, Nur Haidah Binte Mohamad Kamal¹, Wenqin Wu¹

Affiliation

¹ Institute of Chemical and Engineering Sciences (ICES) , Agency for Science, Technology and Research (A*STAR) , 8 Biomedical Grove, Neuros #07-01 , Singapore 138665 , Singapore.

PMID: 31496246
DOI: 10.1021/acs.joc.9b02105

Abstract

A catalyst system comprising CoCl₂/IAd·HBF₄ enables the Suzuki-Miyaura cross-coupling reaction of a broad range of aryl triflates and arylboronic esters that are activated by n-butyllithium.

Publication types

Research Support, Non-U.S. Gov't