Lithium Titanate Cuboid Arrays Grown on Carbon Fiber Cloth for High-Rate Flexible Lithium-Ion Batteries

Abstract

High-rate performance flexible lithium-ion batteries are desirable for the realization of wearable electronics. The flexibility of the electrode in the battery is a key requirement for this technology. In the present work, spinel lithium titanate (Li₄ Ti₅ O₁₂ , LTO) cuboid arrays are grown on flexible carbon fiber cloth (CFC) to fabricate a binder-free composite electrode (LTO@CFC) for flexible lithium-ion batteries. Experimental results show that the LTO@CFC electrode exhibits a remarkably high-rate performance with a capacity of 105.8 mAh g^-1 at 50C and an excellent electrochemical stability against cycling (only 2.2% capacity loss after 1000 cycles at 10C). A flexible full cell fabricated with the LTO@CFC as the anode and LiNi_0.5 Mn_1.5 O₄ coated on Al foil as the cathode displays a reversible capacity of 109.1 mAh g^-1 at 10C, an excellent stability against cycling and a great mechanical stability against bending. The observed high-rate performance of the LTO@CFC electrode is due to its unique corn-like architecture with LTO cuboid arrays (corn kernels) grown on CFC (corn cob). This work presents a new approach to preparing LTO-based composite electrodes with an architecture favorable for ion and electron transport for flexible energy storage devices.

Keywords: flexible electrodes; lithium titanate; lithium-ion battery; rate capability.