Ecofriendly synthesized reduced graphene oxide embellished marsh marigold-like zinc oxide nanocomposite based on ultrasonication technique for the sensitive detection of environmental pollutant hydroquinone

Deepak Balram; Kuang-Yow Lian; Neethu Sebastian

doi:10.1016/j.ultsonch.2019.104650

Ecofriendly synthesized reduced graphene oxide embellished marsh marigold-like zinc oxide nanocomposite based on ultrasonication technique for the sensitive detection of environmental pollutant hydroquinone

Ultrason Sonochem. 2019 Nov:58:104650. doi: 10.1016/j.ultsonch.2019.104650. Epub 2019 Jun 18.

Authors

Deepak Balram¹, Kuang-Yow Lian², Neethu Sebastian³

Affiliations

¹ Department of Electrical Engineering, National Taipei University of Technology, No. 1, Section 3, Zhongxiao East Road, Taipei 106, Taiwan, Republic of China.
² Department of Electrical Engineering, National Taipei University of Technology, No. 1, Section 3, Zhongxiao East Road, Taipei 106, Taiwan, Republic of China. Electronic address: kylian@ntut.edu.tw.
³ Department of Organic and Polymeric Materials, National Taipei University of Technology, No. 1, Section 3, Zhongxiao East Road, Taipei 106, Taiwan, Republic of China.

PMID: 31450365
DOI: 10.1016/j.ultsonch.2019.104650

Abstract

A novel electrochemical sensor using reduced graphene oxide (RGO) decorated marsh marigold-like zinc oxide (ZnO) nanocomposite for the detection of hydroquinone (HQ) is detailed in this paper. We have adopted an ecofriendly preparation procedure for the synthesis of RGO and the synthesis of marsh marigold-like ZnO is carried out using aqueous solution method. The RGO/ZnO nanocomposite is prepared based on ultrasonication technique using a high-intensity ultrasonic bath DC200H (200 W/cm², 40 kHz) and is followed by its precise fabrication on glassy carbon electrode (GCE). Characterizations including X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared (FT-IR) spectroscopy, Raman spectroscopy, and UV visible spectroscopy of ZnO nanoparticles, RGO, and RGO/ZnO nanocomposite are analyzed in this work. Different electrochemical studies were performed in this work to investigate performance of the proposed electrochemical sensor and cyclic voltammetry (CV) and differential pulse voltammetry (DPV) techniques are used to achieve this. The oxidation and reduction peak currents of RGO/ZnO modified GCE exhibited sharp peaks at very low potential of 0.13 V and 0.06 V respectively. We have obtained a high sensitivity of 8.08 μA μM^-1 cm^-2, ultra-low limit of detection (LOD) value of 0.01 μM, and a broad linear range of 0.1-92 μM for the proposed sensor. Moreover, the fabricated sensor exhibited excellent selectivity, good reproducibility, stability, and repeatability revealing the high efficiency of the proposed sensor. Furthermore, experiments were conducted to examine the practical feasibility of the developed sensor. The electrochemical studies conducted as part of the work shows that RGO/ZnO nanocomposite is an apt material for the highly sensitive and efficient detection of HQ.

Keywords: Electrochemical sensor; Hydroquinone; Reduced graphene oxide; Ultrasonication; Zinc oxide.