Valorization of alum sludge via a pyrolysis platform using CO2 as reactive gas medium

Abstract

In an effort to seek a new technical platform for disposal of drinking water treatment sludge (DWTS: alum sludge), pyrolysis of DWTS was mainly investigated in this study. To establish a more sustainable thermolytic platform for DWTS, this study particularly employed CO₂ as reactive gas medium. Thus, this study laid great emphasis on elucidating the mechanistic roles of CO₂ during the thermolysis of DWTS. A series of the TGA tests of DWTS in CO₂ in reference to N₂ revealed no occurrence of the heterogeneous reaction between CO₂ and the sample surface of DWTS. As such, at the temperature regime before initiating the Boudouard reaction (i.e., ≥700 °C), the mass decay patterns of DWTS in N₂ and CO₂ were nearly identical. However, the gaseous effluents from lab-scale pyrolysis of DWTS in CO₂ in reference to N₂ were different. In sum, the homogeneous reactions between CO₂ and volatile matters (VMs) evolved from the thermolysis of DWTS led to the enhanced generation of CO. Also, CO₂ suppressed dehydrogenation of VMs. Such the genuine mechanistic roles of CO₂ in the thermolysis of DWTS subsequently led to the compositional modifications of the chemical species in pyrolytic oil. Furthermore, the biochar composite was obtained as byproduct of pyrolysis of DWTS. Considering that the high content of Al₂O₃ and Fe-species in the biochar composite imparts a strong affinity for As(V), the practical use of the biochar composite as a sorptive material for arsenic (V) was evaluated at the fundamental levels. This work reported that adsorption of As(V) onto the biochar composite followed the pseudo-second order model and the Freundlich isotherm model.

Keywords: Alum sludge; As adsorption; Biochar; CO(2); Pyrolysis; Valorization.