Kagomé lattice magnets have emerged as a versatile platform on which to discover and explore the underlying physics of quantum-spin liquids and related states of matter, although experimental examples of ideal kagomé lattices remain rare. Here we report that Na2Ti3Cl8 is an ideal realization of an insulating S = 1 kagomé magnet. This material undergoes a discrete two-step trimerization upon cooling, transforming from a centrosymmetric, paramagnetic high-temperature (HT) R3m phase to noncentrosymmetric, polar, and trimerized intermediate- (IT) and low-temperature (LT) R3m phases via two successive first-order phase transitions. Symmetry mode decomposition analysis shows that trimerization requires activation of the proper polar order parameter Γ2- and that this mode becomes active at the HT → IT phase transition. The magnitude of this order parameter approximately doubles at the IT → LT transition, with possible activation of a second polar mode, corresponding to Na2 and Ti3Cl8 displacing layers toward each other, at the IT → LT transition. Specific heat measurements reveal comparable changes in entropy between the LT → IT transition, 18.6(1.0) J (mol of f.u.)-1 K-1, and the IT → LT transition, 16.8(1.0) J (mol of f.u.)-1 K-1, demonstrating loss of the magnetic degrees of freedom and constraining possible models for the magnetic and electronic structures of the IT and LT phases. Thus, Na2Ti3Cl8 demonstrates a novel mechanism to obtain polar structures driven by geometrically frustrated lattices and metal-metal bonding and highlights the rich physics arising from kagomé lattice materials.