Anion and pH dependent molecular motion by a halogen bonding [2]rotaxane

Chem Commun (Camb). 2019 Aug 15;55(67):9975-9978. doi: 10.1039/c9cc04752b.

Abstract

A bistable [2]rotaxane containing a halogen bonding benzimidazole-iodotriazole station directly conjugated to a naphthalimide station axle component is demonstrated to undergo macrocycle shuttling translocation only upon both protonation and chloride anion recognition. A naked-eye detectable colour response results from the co-conformational change of the host structure.