Different pollutants affect electrical characteristics of soil, e.g., electric resistivity and capacity. The most extensively used non-intrusive methods in mapping these physical characteristics are electrical method. To better understand the effect of different hydrogeological and environmental process on resistivity and phase of complex resistivity under water-saturated soil, we carried out a controlled laboratory experiment where the host material was simulated by sand soil and the hydrogeological and environmental processes by groundwater table rise, seawater intrusion and heavy metal contamination. The experiment measured the resistivity and phase of soil saturated and unsaturated, with different pollutants added, together with their time-lapse change in a well-controlled column. With the involvement of more measurement parameters, complex resistivity method can provide more information than resistivity method, thereby having better performance in the detection and monitoring of changes in electrical properties of complex contaminated sites. For example, it is capable of discriminating the different contamination process, in this case, e.g., seawater intrusion and heavy metal contamination. In addition, it is still sensitive to the change of pollutant concentration even in site with high added concentration. Furthermore, simulating the saltwater-intruded site contaminated by manganese, it was found that the change of resistivity (ρ) can hardly be observed, while the responses of phase (φ) are so obvious that can be clearly observed.