Synthesis of novel Sn1-xZnxO-chitosan nanocomposites: Structural, morphological and luminescence properties and investigation of antibacterial properties

Int J Biol Macromol. 2019 Oct 1:138:546-555. doi: 10.1016/j.ijbiomac.2019.07.120. Epub 2019 Jul 20.

Abstract

In recent times, metal oxide-organic nanocomposites have received great attention because of their feasibility to wide range applications such as super capacitors, antibacterial activity, biomedical sensors, battery applications and microfluidic devices. In this work, zinc oxide-chitosan (ZnO-CS) and their novel tin zinc oxide-chitosan (Sn1-xZnxO-CS) hybrid nanocomposites successfully synthesized by a simple one-pot sol-gel reaction. The equal metal oxide ratio such as 0.5, 1.0, 1.5 and 2.0% (W/V) for zinc and tin sources with constant weight of chitosan were used to prepare the Sn1-xZnxO-CS nanocomposites. Fourier transform infrared spectroscopy results proved the formation of Sn1-xZnxO-CS nanocomposites. X-ray diffraction patterns discovered the mixed phase polycrystalline nature of Sn1-xZnxO-CS nanocomposites. Optical and luminescence properties were extensively studied for nanocomposites by UV-Vis and photoluminescence spectroscopy, respectively. The surface modification elaborately discussed with scanning electron microscope images due to incorporation of SnOx with ZnO-CS matrix. The antibacterial properties of Sn1-xZnxO-CS were tested against Escherichia coli, Salmonella Typhi and Klebseilla Pneumoniae bacterial species.

Keywords: Antibacterial; Chitosan; Nanocomposites; Sn(1-x)Zn(x)O; ZnO.

MeSH terms

  • Anti-Bacterial Agents / chemistry
  • Anti-Bacterial Agents / pharmacology
  • Chitin / chemistry
  • Chitosan / chemistry*
  • Luminescence
  • Microbial Sensitivity Tests
  • Nanocomposites / chemistry*
  • Nanocomposites / ultrastructure
  • Spectroscopy, Fourier Transform Infrared
  • Structure-Activity Relationship
  • Tin / chemistry*
  • X-Ray Diffraction
  • Zinc Oxide / chemistry*

Substances

  • Anti-Bacterial Agents
  • Chitin
  • Tin
  • Chitosan
  • Zinc Oxide