Aluminium oxide (Al2 O3 ) has widely been used for catalysts, insulators, and composite materials for diverse applications. Herein, we demonstrated if γ-Al2 O3 was useful as a luminescence support material for europium (Eu) (III) activator ion. The hydrothermal method and post-thermal treatment at 800°C were employed to synthesize Eu(III)-doped γ-Al2 O3 nanofibre structures. Luminescence characteristics of Eu(III) ions in Al2 O3 matrix were fully understood by taking 2D and 3D-photoluminescence imaging profiles. Various sharp emissions between 580 to 720 nm were assigned to the 5 D0 →7 FJ (J = 0, 1, 2, 3, 4) transitions of Eu(III) activators. On the basis of X-ray diffraction crystallography, Auger elemental mapping and the asymmetry ratio, Eu(III) ions were found to be well doped into the γ-Al2 O3 matrix at a low (1 mol%) doping level. A broad emission at 460 nm was substantially increased upon higher (2 mol%) Eu(III) doping due to defect creation. The first 3D photoluminescence imaging profiles highlight detailed understanding of emission characteristics of Eu(III) ions in Al oxide-based phosphor materials and their potential applications.
Keywords: asymmetry ratioEu(III)-dopedphotoluminescence imaging; γ-Al2O3.
© 2019 John Wiley & Sons, Ltd.