Large volume liquid state scalar Overhauser dynamic nuclear polarization at high magnetic field

Thierry Dubroca; Sungsool Wi; Johan van Tol; Lucio Frydman; Stephen Hill

doi:10.1039/c9cp02997d

Large volume liquid state scalar Overhauser dynamic nuclear polarization at high magnetic field

Phys Chem Chem Phys. 2019 Oct 2;21(38):21200-21204. doi: 10.1039/c9cp02997d.

Authors

Thierry Dubroca¹, Sungsool Wi, Johan van Tol, Lucio Frydman, Stephen Hill

Affiliation

¹ NHMFL, 1800 E. Paul Dirac Dr, Tallahassee, FL 32310, USA. dubroca@magnet.fsu.edu.

PMID: 31310269
DOI: 10.1039/c9cp02997d

Abstract

Dynamic Nuclear Polarization (DNP) can increase the sensitivity of Nuclear Magnetic Resonance (NMR), but it is challenging in the liquid state at high magnetic fields. In this study we demonstrate significant enhancements of NMR signals (up to 70 on 13C) in the liquid state by scalar Overhauser DNP at 14.1 T, with high resolution (∼0.1 ppm) and relatively large sample volume (∼100 μL).