Fluorescent carbon dots functionalization

Abstract

Carbon dots (CDs), as a new type of luminescent zero-dimensional carbon nanomaterial, have been applied in a variety of fields. Currently, functionalization of CDs is an extremely useful method for effectively tuning their intrinsic structure and surface state. Heteroatom doping and surface modification are two functionalization strategies for improving the photophysical performance and broadening the range of applications for fluorescent CDs. Heteroatom doping in CDs can be used to tune their intrinsic properties, which has received significant research interests because of its simplicity. Surface modification can be applied for varying active sites and the functional groups on the CDs surface, which can endow fluorescent CDs with the unique properties resulting from functional ligand. In this review, we summarize the structural and physicochemical properties of functional CDs. We focused our review on the latest developments in functionalization strategies for CDs and discuss the detailed characteristics of different functionalization methods. Ultimately, we hope to inform researchers on the latest progress in functionalization of CDs and provide perspectives on future developments for functionalization of CDs and their potential applications.

Keywords: Carbon dots; Functionalization; Heteroatom doping; Surface modification.