Linkage induced enhancement of fluorescence in metal-carbene bond directed metallacycles and metallacages

Chem Commun (Camb). 2019 Jul 11;55(57):8309-8312. doi: 10.1039/c9cc04444b.

Abstract

Two new 1,4-dihydropyrrolo[3,2-b]pyrrole based aggregation induced emission (AIE)-inactive di- and tetra-imidazolium salts were employed with Ag(i) for the synthesis of a Ag-carbene bond directed metallacycle (1) and metallacage (2), respectively. Transmetalation of these complexes allowed their facile conversion to their respective Au(i)-metallacycle (3) and metallacage (4). The final assemblies exhibit linkage induced enhancement of fluorescence (LIEF). The free ligands are almost non-fluorescent (ΦF = 3.2, 3.4) in comparison to their metal-carbene counterparts (ΦF up to 32.0). Thus, without using any AIEgen, obtaining high emission efficiencies in complexes AgI-CNHC (1, 2) via linkage is a nice approach towards turn-on fluorescence.