Abstract
The total synthesis of putative penasulfate A was effectively achieved by a convergent strategy with a longest linear sequence of 14 steps and overall yield of 8.6%. The highlights of our strategy involved an E-selective olefin cross-metathesis, Suzuki cross-coupling, and a copper(I)-catalyzed coupling reaction.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Alkenes / chemistry
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Arabinose / chemistry*
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Catalysis
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Fatty Acids / chemical synthesis*
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Fatty Acids / chemistry*
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Molecular Structure
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Pipecolic Acids / chemical synthesis*
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Pipecolic Acids / chemistry*
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Stereoisomerism
Substances
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Alkenes
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Fatty Acids
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Pipecolic Acids
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penasulfate A
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Arabinose