Oil behavior in sea ice: Changes in chemical composition and resultant effect on sea ice dielectrics

Mar Pollut Bull. 2019 May:142:216-233. doi: 10.1016/j.marpolbul.2019.03.021. Epub 2019 Mar 28.

Abstract

There has been increasing urgency to develop methods for detecting oil in sea ice owing to the effects of climate change in the Arctic. A multidisciplinary study of crude oil behavior in a sea ice environment was conducted at the University of Manitoba during the winter of 2016. In the experiment, medium-light crude oil was injected underneath young sea ice in a mesocosm. The physical and thermodynamic properties of the oil-infiltrated sea ice were monitored over a three-week time span, with concomitant analysis of the oil composition using analytical instrumentation. A resonant perturbation technique was used to measure the oil dielectric properties, and the contaminated sea ice dielectric properties were modeled using a mixture model approach. Results showed that the interactions between the oil and sea ice altered their physical and thermodynamic properties. These changes led to an overall decrease in sea ice dielectrics, potentially detectable by remote sensing systems.

Keywords: Arctic sea ice; Dielectrics; Oil composition; Oil weathering; Petroleum hydrocarbons; Remote sensing.

MeSH terms

  • Arctic Regions
  • Ice Cover*
  • Models, Theoretical
  • Petroleum / analysis*
  • Petroleum Pollution / analysis
  • Spectrophotometry, Infrared
  • Thermodynamics
  • Water Pollutants, Chemical / analysis*
  • Water Pollutants, Chemical / chemistry*

Substances

  • Petroleum
  • Water Pollutants, Chemical