Microstructure and Mechanical Properties of Spark Plasma Sintered Si3N4/WC Ceramic Tools

Materials (Basel). 2019 Jun 10;12(11):1868. doi: 10.3390/ma12111868.

Abstract

Silicon nitride (Si3N4) based ceramic tools exhibit good machinability in cutting materials such as gray cast iron, ductile iron, malleable cast iron, and superalloys due to excellent high-temperature mechanical properties. In this paper, high-performance Si3N4-based ceramic tools containing tungsten carbide (WC) and cobalt (Co) were studied. Effects of the WC content and Co content on mechanical properties and a microstructure of Si3N4-based ceramic materials were analyzed. Results showed that Si3N4-based ceramic material containing 10 wt % WC and 1 wt % Co had the best comprehensive mechanical properties at a sintering temperature of 1650 °C and holding time of 6 min, achieving Vickers hardness, fracture toughness, and room temperature bending strength of 16.96 GPa, 7.26 MPa·m1/2, and 1132 MPa, respectively. The microstructure of Si3N4-based ceramic tool material is uniform without obvious abnormal growth. The Si3N4-based ceramic tool was mainly composed of α-Si3N4, β-Si3N4, and WC phases.

Keywords: mechanical properties; silicon nitride; spark plasma sintered; tungsten carbide.