Coordinated Molecule-Modulated Magnetic Phase with Metamagnetism in Metal-Organic Frameworks

Kwanghyo Son; Jin Yeong Kim; Gisela Schütz; Sung Gu Kang; Hoi Ri Moon; Hyunchul Oh

doi:10.1021/acs.inorgchem.9b00889

Coordinated Molecule-Modulated Magnetic Phase with Metamagnetism in Metal-Organic Frameworks

Inorg Chem. 2019 Jul 15;58(14):8895-8899. doi: 10.1021/acs.inorgchem.9b00889. Epub 2019 Jun 11.

Authors

Kwanghyo Son¹, Jin Yeong Kim², Gisela Schütz¹, Sung Gu Kang³, Hoi Ri Moon², Hyunchul Oh⁴

Affiliations

¹ Max Planck Institute for Intelligent Systems , Heisenbergstrasse 3 , Stuttgart 70569 , Germany.
² Department of Chemistry , Ulsan National Institute of Science and Technology , Ulsan 44919 , Republic of Korea.
³ School of Chemical Engineering , University of Ulsan , Ulsan 44610 , Republic of Korea.
⁴ Department of Energy Engineering , Gyeongnam National University of Science and Technology , Jinju 52725 , Republic of Korea.

PMID: 31184874
DOI: 10.1021/acs.inorgchem.9b00889

Abstract

Most well-known metal-organic frameworks (MOFs) possessing the magnetic Ni₂O₂(CO₂)₂ chains, called Ni-MOF-74, have been investigated with regard to magnetic properties at open-metal sites. We present the modulation of their magnetic phase and metamagnetism via imidazole molecule coordination.