Abstract: Stable radicals in organic conjugated molecules are of great interest due to their magnetic signals and broad optical absorptions. In this paper, we report on naphthalene, benzoperylene, perylene, terrylene, and quaterrylene carboximides, reduced under controlled conditions, where stable metal-free solid salts of radical anions could be obtained forming darkly colored solutions with line-rich UV/Vis/NIR spectra and exhibiting special magnetic properties. The most bathochromic shift of the absorption maxima extend from 760 until 1700 nm. Persistent paramagnetic properties of the solids were observed and temperature-dependent susceptibilities are measured.
Keywords: Absorption; Electron spin resonance; Fluorescence; Perylenes; Photochemistry; Radical anions.