To what extent do polymeric stabilizers affect nanoparticles characteristics?

Abstract

Colloidal synthesis of nanoparticles using polymeric stabilizers as a template of a structure directing agent provided a plethora of opportunities in fabricating nanoparticles (NPs) with controlled size, shape, composition and structural characteristics. To understand the complete potency of polymeric stabilizers during the synthesis of nanoparticles, the relationship between polymer characteristics such as structure, molecular weight and concentration and nanoparticles characteristics is discussed in depth. This review portrays the use of polymers to attain nanostructured materials via covalent and non-covalent approaches. These polymers can also serve as surfaces modifier as well as the growth regulators during the synthesis of nanomaterials. The effect provided by polymers that directs the formation of nanomaterials into desired forms is otherwise hard to achieve. We especially spotlight on the approaches for tuning the characteristic properties of nanoparticles via cautious choice of the polymer system with special focus to stimuli-responsive polymers. This review mainly focusses on answering the main challenging question; what is the ideal polymeric stabilizer system to obtain specific morphology, size and phase structure of nanoparticles? Such vital information will enable rational design of nanoparticles to meet specific needs for different applications.

Keywords: Colloidal stability; Nanoparticles; Polymeric stabilizers; Steric stabilization; Stimuli-responsive polymers.