Sewage sludge ash recovery as valuable raw material for chemical stabilization of leachable heavy metals

Abstract

This paper proposes, for the first time, the use of sewage sludge ash (SSA), obtained by sludge combustion for the stabilization of fly ashes containing heavy metals as Pb and Zn. In particular, the proposed method aims to take advantage of valuable raw materials present in SSA, such as phosphate, silica, and alumina. The stabilization has been explained by the synergic phosphate, carbonation, and pozzolanic reactions together with the Friedel's salt formation. This method to sewage sludge management allows the complete recovery of valuable raw materials otherwise destinated for lanfill. This is virtuous example of the use of waste materials for de-pollution processes.

Keywords: Municipal solid waste incineration (MSWI) fly ash; Sewage sludge; Sewage sludge ash recovery; Stabilization mechanism; Waste.